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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Reaction rate ： ウィキペディア英語版 Reaction rate The reaction rate (rate of reaction) or speed of reaction for a reactant or product in a particular reaction is intuitively defined as how fast or slow a reaction takes place. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second. Chemical kinetics is the part of physical chemistry that studies reaction rates. The concepts of chemical kinetics are applied in many disciplines, such as chemical engineering, enzymology and environmental engineering. ==Formal definition of reaction rate== Consider a typical chemical reaction: :''a''A + ''b''B → ''p''P + ''q''Q The lowercase letters (''a'', ''b'', ''p'', and ''q'') represent stoichiometric coefficients, while the capital letters represent the reactants (A and B) and the products (P and Q). According to IUPAC's Gold Book definition〔(IUPAC definition of rate of reaction )〕 the reaction rate ''r'' for a chemical reaction occurring in a closed system under isochoric conditions, without a build-up of reaction intermediates, is defined as: :$r\; =\; -\; \backslash frac\; \backslash frac\; =\; -\; \backslash frac\; \backslash frac\; =\; \backslash frac\; \backslash frac\; =\; \backslash frac\; \backslash frac$ where () denotes the concentration of the substance X. (Note: The rate of a reaction is always positive. A negative sign is present to indicate the reactant concentration is decreasing.) The IUPAC〔 recommends that the unit of time should always be the second. In such a case the rate of reaction differs from the rate of increase of concentration of a product P by a constant factor (the reciprocal of its stoichiometric number) and for a reactant A by minus the reciprocal of the stoichiometric number. Reaction rate usually has the units of mol L−1 s−1. It is important to bear in mind that the previous definition is only valid for a ''single reaction'', in a ''closed system'' of ''constant volume''. This usually implicit assumption must be stated explicitly, otherwise the definition is incorrect: If water is added to a pot containing salty water, the concentration of salt decreases, although there is no chemical reaction. For any open system, the full mass balance must be taken into account: ''IN - OUT + GENERATION - CONSUMPTION = ACCUMULATION'' :$F\_\; -\; F\_A\; +\; \backslash int\_^\; v\backslash ,\; dV\; =\; \backslash frac$, where $F\_$ is the inflow rate of A in molecules per second, $F\_A$ the outflow, and $v$ is the instantaneous reaction rate of A (in number concentration rather than molar) in a given differential volume, integrated over the entire system volume $V$ at a given moment. When applied to the closed system at constant volume considered previously, this equation reduces to: $r=\; \backslash frac$, where the concentration $()$ is related to the number of molecules $N\_A$ by $()\; =\; \backslash frac$. Here $N\_0$ is the Avogadro constant. For a single reaction in a closed system of varying volume the so-called ''rate of conversion'' can be used, in order to avoid handling concentrations. It is defined as the derivative of the extent of reaction with respect to time. $r\; =\backslash frac\; =\; \backslash frac\; \backslash frac\; =\; \backslash frac\; \backslash frac\; =\; \backslash frac\; \backslash left(V\backslash frac\; +\; C\_i\; \backslash frac\; \backslash right)$ Here $\backslash scriptstyle\; \backslash nu\_i$ is the stoichiometric coefficient for substance $i$, equal to ''a'', ''b'', ''p'', and ''q'' in the typical reaction above. Also $\backslash scriptstyle\; V$ is the volume of reaction and $\backslash scriptstyle\; C\_i$ is the concentration of substance $i$. When side products or reaction intermediates are formed, the IUPAC〔 recommends the use of the terms rate of appearance and rate of disappearance for products and reactants, properly. Reaction rates may also be defined on a basis that is not the volume of the reactor. When a catalyst is used the reaction rate may be stated on a catalyst weight (mol g−1 s−1) or surface area (mol m−2 s−1) basis. If the basis is a specific catalyst site that may be rigorously counted by a specified method, the rate is given in units of s−1 and is called a turnover frequency. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Reaction rate」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.